The Inorganic-Organic Hybrid Compound {[Mn(trien)]2SnS4}•4H2O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS4]4- Tetrahedron

被引：44

作者：

Pienack, Nicole ^{[1
]}

Naether, Christian ^{[1
]}

Bensch, Wolfgang ^{[1
]}

机构：

[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 12期

关键词：

Tin; Sulfur; Structure elucidation; Organic-inorganic hybrid composites; Coordination modes; TIN SULFIDE MATERIALS; CRYSTAL-STRUCTURES; SOLVOTHERMAL SYNTHESIS; SPECTROSCOPIC PROPERTIES; THIOSTANNATES; TRANSITION; COMPLEXES; IONS;

D O I：

10.1002/ejic.200801093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound {[Mn(C6H18N4)](2)SnS4}center dot 4H(2)O (C6H18N4 = triethylenetetramine) was obtained under solvothermal conditions. In the structure of the {[Mn(C6H18N4)](2)SnS4}(infinity), chain, two S atoms of the [SnS4](4)(-) anion act. in a hitherto never observed mu(3) bridging mode that connects the Mn2S2N8 di-octahedra. The Mn2+ ions are octahedrally coordinated by four N and two S atoms, and two symmetry-related octahedra share a common S-S edge. Three of the H2O molecules are joined into chains through H-bonding interactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：1575 / 1577

页数：3

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