Two hybrid materials assembled from transition metal mono-substituted Keggin polyoxoanions as photocatalysts under visible light

被引:22
作者
Song, Bai-Qiao [1 ]
Wang, Xin-Long [1 ]
Liang, Jun [1 ]
Zhang, Yu-Teng [1 ]
Shao, Kui-Zhan [1 ]
Su, Zhong-Min [1 ]
机构
[1] NE Normal Univ, Minist Educ, Key Lab Polyoxometalate Sci, Inst Funct Mat Chem, Changchun 130024, Jilin, Peoples R China
关键词
BUILDING-BLOCKS; POLYOXOMETALATE; DERIVATIVES; DAWSON; POLYOXOTUNGSTATES; FUNCTIONALIZATION; HETEROPOLYANIONS; DIVERSITY; ANIONS; CHAIN;
D O I
10.1039/c4ce01148a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two 2D isostructural organic-inorganic hybrid solid materials based on transition metal mono-substituted Keggin polyoxotungstate with an antenna molecule were synthesized under hydrothermal conditions. Compound 2 with the substituted Co(II) exhibits good photocatalytic activity in the degradation of rhodamine-B (RB) under visible light irradiation.
引用
收藏
页码:9163 / 9167
页数:5
相关论文
共 49 条
[1]   Synthesis, characterization, and photochemical behavior of {Ru(arene)2+ derivatives of α-[PW11O39]7-:: An organometallic way to ruthenium-substituted heteropolytungstates [J].
Artero, V ;
Laurencin, D ;
Villanneau, R ;
Thouvenot, R ;
Herson, P ;
Gouzerh, P ;
Proust, A .
INORGANIC CHEMISTRY, 2005, 44 (08) :2826-2835
[2]   Organometallic-polyoxometalate hybrid compounds: Metallosalen compounds modified by Keggin type polyoxometalates [J].
Bar-Nahum, I ;
Cohen, H ;
Neumann, R .
INORGANIC CHEMISTRY, 2003, 42 (11) :3677-3684
[3]   Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic-polyoxometalate hybrid compound [J].
Bar-Nahum, I ;
Neumann, R .
CHEMICAL COMMUNICATIONS, 2003, (21) :2690-2691
[4]   Efficient preparation of functionalized hybrid organic/inorganic Wells- Dawson-type polyoxotungstates [J].
Bareyt, S ;
Piligkos, S ;
Hasenknopf, B ;
Gouzerh, P ;
Lacôte, E ;
Thorimbert, S ;
Malacria, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) :6788-6794
[5]   The ruthenium(II)-supported heteropolytungstates [Ru(dmso)3(H2O)-XW11O39]6- (X = Ge, Si) [J].
Bi, LH ;
Kortz, U ;
Keita, B ;
Nadjo, L .
DALTON TRANSACTIONS, 2004, (20) :3184-3190
[6]   Mono-substituted Keggin, Wells-Dawson and {P2W21}-type polyoxometalates without positional disorder [J].
Cao, Rui ;
O'Halloran, Kevin P. ;
Hillesheim, Daniel A. ;
Hardcastle, Kenneth I. ;
Hill, Craig L. .
CRYSTENGCOMM, 2010, 12 (05) :1518-1525
[7]   Photosensitized degradation of dyes in polyoxometalate solutions versus TiO2 dispersions under visible-light irradiation:: Mechanistic implications [J].
Chen, CC ;
Zhao, W ;
Lei, PX ;
Zhao, JC ;
Serponer, N .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (08) :1956-1965
[8]   Photodegradation of dye pollutants catalyzed by porous K3PW12O40 under visible irradiation [J].
Chen, Chuncheng ;
Wang, Qi ;
Lei, Pengxiang ;
Song, Wenjing ;
Ma, Wanhong ;
Zhao, Jincai .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (12) :3965-3970
[9]   Three Transition-Metal Substituted Polyoxotungstates Containing Keggin Fragments: From Trimer to One-Dimensional Chain to Two-Dimensional Sheet [J].
Chen, Lijuan ;
Shi, Dongying ;
Zhao, Junwei ;
Wang, Yulong ;
Ma, Pengtao ;
Wang, Jingping ;
Niu, Jingyang .
CRYSTAL GROWTH & DESIGN, 2011, 11 (05) :1913-1923
[10]   Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].
Cook, Timothy R. ;
Zheng, Yao-Rong ;
Stang, Peter J. .
CHEMICAL REVIEWS, 2013, 113 (01) :734-777