Gold(I) Chloride Coordinated 3-Hexyne

被引：49
作者：
Wu, Jiang [1 ]
Kroll, Peter [1 ]
Dias, H. V. Rasika [1 ]
机构：
[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 02期
关键词：
CRYSTAL-STRUCTURE; COMPLEXES; CATALYSIS; ALKYNE; CHEMISTRY; ETHYLENE;
D O I：
10.1021/ic8020854
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A linear gold(I) complex featuring a simple, unstrained alkyne has been synthesized using AuCl and 3-hexyne and characterized using X-ray crystallography. Density functional theory calculations show that sigma donation from alkyne -> Au dominates over the Au -> alkyne pi back-donation.
引用
收藏
页码：423 / 425
页数：3
相关论文
共 47 条
[1]   Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynes [J].
Akana, Jennifer A. ;
Bhattacharyya, Koyel X. ;
Mueller, Peter ;
Sadighi, Joseph P. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) :7736-+
[2]  
[Anonymous], COMPREHENSIVE ORGANO
[3]   Alternative synthetic methods through new developments in catalysis by gold [J].
Arcadi, Antonio .
CHEMICAL REVIEWS, 2008, 108 (08) :3266-3325
[4]   CHLORO(TRIPHENYLPHOSPHINE)GOLD(I) [J].
BAENZIGER, NC ;
BENNETT, WE ;
SOBOROFF, DM .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (MAR15) :962-963
[5]  
BOESE R, 1999, ACTA CRYSTALLOGRAP C, V0055
[6]  
Bond GC, 2006, CATALY SCI SER, V6, P1, DOI 10.1142/9781860948954
[7]   Golden opportunities in stereoselective catalysis [J].
Bongers, Nadine ;
Krause, Norbert .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (12) :2178-2181
[8]   Synthesis and characterization of new silver complexes of alkynes. Single-crystal structures of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(diphenylacetylene)silver and tetrakis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)bis(4-octyne)tetrasilver [J].
Chi, KM ;
Lin, CT ;
Peng, SM ;
Lee, GH .
ORGANOMETALLICS, 1996, 15 (11) :2660-2663
[9]   Synthesis and properties of gold alkene complexes.: Crystal structure of [Au(bipyoXyl)(η2-CH2=CHPh)](PF6) and DFT calculations on the model cation [Au(bipy)(η2-CH2=CH2)] [J].
Cinellu, Maria A. ;
Minghetti, Giovanni ;
Cocco, Fabio ;
Stoccoro, Sergio ;
Zucca, Antonio ;
Manassero, Mario ;
Arca, Massimiliano .
DALTON TRANSACTIONS, 2006, (48) :5703-5716
[10]  
DELLAMICO DB, 1987, ORGANOMETALLICS, V6, P1207
12345