Self-assembly of a one-dimensional silver complex containing two kinds of helical chains

被引：0

作者：

Sun, DF ^{[1
]}

Cao, R ^{[1
]}

Sun, YQ ^{[1
]}

Bi, WH ^{[1
]}

Li, XH ^{[1
]}

Hong, MC ^{[1
]}

Zhao, YJ ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 01期

关键词：

self-assembly; S ligands; N ligands; silver; helical structures;

D O I：

10.1002/ejic.200390003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of the potassium sulfonate salt K(2)pesp [H(2)pesp = piperazine-1,4-bis(2-ethanesulfonic acid] with piperazine (PIP) and a silver(I) salt in solution allows the preparation of a novel one-dimensional helical polymer [Ag(PIP)](n).[Ag(pesd)](n).2nH(2)O (1), which is made up of two independent silver-containing helical chains, namely [Ag- (PIP)](n) and [Ag(pesd)](n). There is no direct bonding interaction between the two chains, and the hydrogen bonds between the chains give 1 a two-dimensional layer supramolecular architecture. ( (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：38 / 41

页数：4

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