Scattering from surface fractals in terms of composing mass fractals

被引:35
作者
Cherny, A. Yu. [1 ,2 ]
Anitas, E. M. [1 ,3 ]
Osipov, V. A. [1 ]
Kuklin, A. I. [1 ,4 ]
机构
[1] Joint Inst Nucl Res, Dubna 141980, Russia
[2] Inst for Basic Sci Korea, Ctr Theoret Phys Complex Syst, Daejeon 34051, South Korea
[3] Horia Hulubei Natl Inst Phys & Nucl Engn, RO-077125 Bucharest, Romania
[4] MIPT, Lab Adv Res Membrane Prot, Moscow, Russia
关键词
small-angle scattering; surface fractals; mass fractals; power-law polydispersity; SMALL-ANGLE SCATTERING; NANOSTRUCTURES; DIFFRACTION; APERTURES; SYSTEMS;
D O I
10.1107/S1600576717005696
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is argued that a finite iteration of any surface fractal can be composed of mass-fractal iterations of the same fractal dimension. Within this assertion, the scattering amplitude of a surface fractal is shown to be a sum of the amplitudes of the composing mass fractals. Various approximations for the scattering intensity of surface fractals are considered. It is shown that small-angle scattering (SAS) from a surface fractal can be explained in terms of a power-law distribution of sizes of objects composing the fractal (internal polydispersity), provided the distance between objects is much larger than their size for each composing mass fractal. The power-law decay of the scattering intensity I(q) proportional to q(Ds-6), where 2 < D-s < 3 is the surface-fractal dimension of the system, is realized as a non-coherent sum of scattering amplitudes of three-dimensional objects composing the fractal and obeying a power-law distribution dN(r) proportional to r(-tau) dr, with D-s = iota - 1. The distribution is continuous for random fractals and discrete for deterministic fractals. A model of the surface deterministic fractal is suggested, the surface Cantor-like fractal, which is a sum of three-dimensional Cantor dusts at various iterations, and its scattering properties are studied. The present analysis allows one to extract additional information from SAS intensity for dilute aggregates of single-scaled surface fractals, such as the fractal iteration number and the scaling factor.
引用
收藏
页码:919 / 931
页数:13
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