Ru(III) catalysed oxidation of 2-propanol by Cr(VI) in micellar media

被引：39

作者：

Chowdhury, Suman ^{[1
]}

Rakshit, Atanu ^{[1
]}

Acharjee, Animesh ^{[1
,2
]}

Ghosh, Aniruddha ^{[3
]}

Mahali, Kalachand ^{[3
]}

Saha, Bidyut ^{[1
]}

机构：

[1] Univ Burdwan, Dept Chem, Homogeneous Catalysis Lab, Burdwan 713104, WB, India

[2] Hooghly Mohsin Coll, Dept Chem, Chinsura, WB, India

[3] Univ Kalyani, Dept Chem, Kalyani 741235, WB, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 290卷

关键词：

2-Propanol oxidation; Ru(III) metal catalysis; SDS micellar medium; Ionic interaction; CHROMIC-ACID OXIDATION; HETEROAROMATIC NITROGEN BASE; CHROMIUM(VI) OXIDATION; CERIUM(IV) OXIDATION; ROOM-TEMPERATURE; AQUEOUS-MEDIA; TRITON X-100; RU(III)-CATALYZED OXIDATION; SECONDARY ALCOHOLS; RATE ENHANCEMENT;

D O I：

10.1016/j.molliq.2019.111247

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Acetone, the simplest ketone of abundant useful is produced from 2-propanol by oxidation with hexavalent Cr (VI) sluggishly under pseudo 1st order reaction condition. The rate is enhanced considerably using Ru(III) metal salt solution at ppm level as a catalyst. Additional rate enhancement, is obtained in SDS micellar media, is reflected in rapid reduction of peak height of absorbance curve of the oxidant Cr(VI) at lambda(max) = 440 nm. The product, acetone is confirmed by IR spectrum of 2, 4- DNP derivative and H-1 NMR study of acetone. (C) 2019 Elsevier B.V. All rights reserved.

引用

页数：9

共 56 条

[1] Micellar catalysed and heteroaromatic base promoted rate enhancement of oxidation of an alicyclic alcohol in aqueous medium [J].