An acid-pasting strategy towards PTCDA based high performance lithium/sodium ion battery cathodes

被引：34
作者：
Jing, Fan [1 ]
Huang, Tao [1 ]
Tao, Guangzhi [1 ]
Ma, Lie [1 ]
Lu, Deng [1 ]
Liu, Ruili [2 ]
Xi, Xin [2 ]
Wu, Dongqing [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, 800 Dongchuan RD, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, Dept Elect Engn, Natl Engn Lab TFT LCD Mat & Technol, 800 Dongchuan RD, Shanghai 200240, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2018年 / 276卷
基金：
中国国家自然科学基金;
关键词：
Acid-pasting; PTCDA; Organic cathode; Lithium ion battery; Sodium ion battery; ORGANIC ELECTRODE MATERIALS; STORAGE DEVICES; ENERGY-STORAGE; POLYMER; NANOCOMPOSITE; CHALLENGES; PERYLENE; GRAPHENE;
D O I：
10.1016/j.electacta.2018.04.155
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
An acid-pasting approach is developed in this work to prepare the composites of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) and carbon black (CB) by mixing both components in concentrated sulfuric acid. Different from the traditional powder processing, the solution-based fabrication strategy easily renders the effective combination of PTCDA and CB in the resultant CB/PTCDA composites, thus greatly improving their electrochemical performances. As the results, the composite with 20 wt% PTCDA shows excellent rate performances as the cathode material for both lithium ion battery (88 mAh g(-1) at 5000 mAg(-1)) and sodium ion battery (100 mAh g(-1) at 1000 mA g(-1)). As a facile and efficient processing strategy, the acid-pasting approach is expected to have wide application in the fabrication of organic electrodes in secondary batteries. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：207 / 213
页数：7
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