Superbenzene-bridged bis(permethyl-β-cyclodextrin) as a convenient and effective probe for trinitrophenol exploder

被引:20
作者
Yu, Jie [1 ]
Chen, Yong [1 ]
Li, Jing-Jing [1 ]
Liu, Yu [1 ,2 ]
机构
[1] Nankai Univ, Dept Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
关键词
BETA-CYCLODEXTRIN; COAXIAL NANOTUBES; HEXABENZOCORONENE; TRIPTYCENE; VAPOR; AGGREGATION; ELECTRONICS; EXPLOSIVES; CONJUGATE; CHEMISTRY;
D O I
10.1039/c6tc05121a
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel planar C-2 symmetrical superbenzene-bridged bis(permethyl-beta-CD) was synthesized by grafting two permethyl-beta-CD units onto a coronene core. Its self-assembly and luminescent behaviors could be smartly controlled by adjusting the polarity of the environment. Significantly, the resultant self-assembly showed specific fluorescence responses to exploders, especially 2,4,6-trinitrophenol, over various common aromatic compounds, which could be readily distinguished either in solution or on the test paper, and the detection limit of self-assembly towards 2,4,6-trinitrophenol could reach the ppb level. This finding would enable the self-assembly as a convenient and highly efficient fluorescence sensor for the detection of exploders.
引用
收藏
页码:799 / 802
页数:4
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