Measurement and Thermodynamic Modeling of Ternary (Liquid plus Liquid) Equilibrium for Extraction of 2-Methyl-3-buten-2-ol from Aqueous Solution with Different Solvents

被引：6
作者：
Liu, Haigang [1 ]
Jia, Bing [2 ]
Sun, Weizhen [1 ]
Dong, Shihua [3 ]
机构：
[1] China Univ Petr East China, Coll Chem Engn, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China
[2] Qingdao Haiwan Grp Co Ltd, Qingdao Haiwan Technol Ind Res Inst Co Ltd, Qingdao 266061, Shandong, Peoples R China
[3] Shandong Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266590, Shandong, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2020年 / 65卷 / 10期
关键词：
SELECTIVE HYDROGENATION; MUTUAL SOLUBILITIES; ETHYL-ACETATE; WATER; MIXTURES; SYSTEMS; UNCERTAINTY;
D O I：
10.1021/acs.jced.0c00667
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Liquid-liquid equilibrium (LLE) data for water + 2-methyl-3-buten-2-ol + (isopropyl ether or 4-methylpentan-2-ol or p-xylene or ethyl acetate) ternary systems was measured at 308.2 K under 101.3 kPa. Distribution coefficients and separation factors were obtained and applied to evaluate the extraction capacity of selected solvents. Furthermore, the experimental LLE data were successfully correlated by the nonrandom two-liquid (NRTL) and universal quasi-chemical (UNIQUAC) models, which showed a root-mean-square deviation (RMSD) of less than 0.78% for all systems.
引用
收藏
页码：5030 / 5036
页数：7
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