Polymer building blocks:: a CuCl2-bridged phosphazene dimer containing κ5N coordinated Cu(II)

被引:40
作者
Ainscough, EW [1 ]
Brodie, AM [1 ]
Depree, CV [1 ]
机构
[1] Massey Univ, Inst Fundamental Sci, Dept Chem, Palmerston North, New Zealand
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 23期
关键词
D O I
10.1039/a908430d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of a hexakis(2-pyridyloxy)cyclotriphosphazene (L) with CuCl2 affords a novel CuCl2-bridged dimer (1) with each monomeric unit also coordinated to Cu(II) via a kappa(5)N binding core; such a dimer represents a potentially new class of polymeric phosphazene-metal complexes.
引用
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页码:4123 / 4124
页数:2
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