C ∼ H Bond Functionalization through Intramolecular Hydride Transfer**

被引：332
作者：
Haibach, Michael C. [1 ]
Seidel, Daniel [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, New Brunswick, NJ 08901 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 20期
基金：
美国国家科学基金会;
关键词：
asymmetric catalysis; cascade reactions; CH functionalization; hydride transfer; redox-neutral reactions; HIGHLY ENANTIOSELECTIVE SYNTHESIS; ACID CATALYZED FORMATION; CHIRAL PHOSPHORIC-ACID; RING-CLOSURE REACTIONS; TRANSFER HYDROGENATION; ASYMMETRIC-SYNTHESIS; PROPARGYLIC AMINES; 1,5-HYDRIDE SHIFTS; ALPHA-CYCLIZATION; 1,3-DISUBSTITUTED ALLENES;
D O I：
10.1002/anie.201306489
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Known for over a century, reactions that involve intramolecular hydride-transfer events have experienced a recent resurgence. Undoubtedly responsible for the increased interest in this research area is the realization that hydride shifts represent an attractive avenue for CH bond functionalization. The redox-neutral nature of these complexity-enhancing transformations makes them ideal for sustainable reaction development. This Review summarizes recent progress in this field while highlighting key historical contributions.
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收藏
页码：5010 / 5036
页数：27
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