Reactions of transition-metal oxo complexes with B(C6F5)3: Crystal structures of [V{OB(C6P5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)] (acac equals acetylacetonate)

被引：37
|
作者：
Galsworthy, JR [1 ]
Green, MLH [1 ]
Muller, M [1 ]
Prout, K [1 ]
机构：
[1] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 08期
关键词：
D O I：
10.1039/a608140a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The transition-metal oxo complexes [VO(acac)(2)],[{TiO(acac)(2)}(2)] and cis-[MoO2(acac)(2)] (acac = C5H7O2) reacted with the strong Lewis acid B(C6F5)(3) to give the structurally characterized complexes [V{OB(C6F5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)]. The M=O-B moiety is essentially linear.
引用
收藏
页码：1309 / 1313
页数：5
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