Reactions of transition-metal oxo complexes with B(C6F5)3: Crystal structures of [V{OB(C6P5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)] (acac equals acetylacetonate)

被引：39

作者：

Galsworthy, JR ^{[1
]}

Green, MLH ^{[1
]}

Muller, M ^{[1
]}

Prout, K ^{[1
]}

机构：

[1] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a608140a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transition-metal oxo complexes [VO(acac)(2)],[{TiO(acac)(2)}(2)] and cis-[MoO2(acac)(2)] (acac = C5H7O2) reacted with the strong Lewis acid B(C6F5)(3) to give the structurally characterized complexes [V{OB(C6F5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)]. The M=O-B moiety is essentially linear.

引用

页码：1309 / 1313

页数：5

共 21 条

[1] MONONUCLEAR AND DINUCLEAR TITANIUM(III) TITANIUM(IV) COMPLEXES WITH 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE(L) - CRYSTAL-STRUCTURES OF A COMPOSITIONALLY DISORDERED GREEN AND A BLUE FORM OF [LTICL3] - STRUCTURES OF [LTI(O)(NCS)2], [LTI(OCH3)BR2](CLO4), AND [L2TI2(O)2F2(MU-F)](PF6) [J].