Nanorods and nanolipsticks structured ZnO photoelectrode for dye-sensitized solar cells

被引:29
作者
Hossain, M. F. [2 ]
Takahashi, T. [1 ]
Biswas, S. [1 ]
机构
[1] Toyama Univ, Grad Sch Sci & Engn Res, Toyama 9308555, Japan
[2] Toyama Univ, Grad Sch Sci & Engn Educ, Toyama 9308555, Japan
关键词
Dye-sensitized solar cells; Zinc oxide; Sol-gel method; Deposition time; Nanorods and nanolipsticks; THIN-FILMS; PHOTOLUMINESCENCE; NANOSTRUCTURES; EFFICIENCY;
D O I
10.1016/j.elecom.2009.07.011
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nanostructured ZnO photoelectrodes were synthesized on SnO2:F (FTO) glass substrate coated with sol-gel based ZnO seed layer via hydrothermal route at various deposition times: 30, 60, 90 and 180 min. Ruthenium based dye and carbon counter electrode were used for the fabrication of dye-sensitized solar cells (DSCs). Interestingly, nanolipsticks structures were found with low deposition times, where two dissimilar nanorods (similar to 111 and 165 nm) attached together. The number of nanolipsticks structures decreased and nanorods increased with increase of deposition time. The DSCs based on ZnO nanorods for 180 min, shows the maximum efficiency, 1.04% at 100 mW/cm(2) light intensity. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1756 / 1759
页数:4
相关论文
共 30 条
[1]   Nanowire-based dye-sensitized solar cells [J].
Baxter, JB ;
Aydil, ES .
APPLIED PHYSICS LETTERS, 2005, 86 (05) :1-3
[2]  
Cullity B.D., 1978, ELEMENTS XRAY DIFFRA, V2nd, P102
[3]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[4]   Dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153
[5]   Hydrothermal growth of perpendicularly oriented ZnO nanorod array film and its photoelectrochemical properties [J].
Guo, M ;
Diao, P ;
Cai, SM .
APPLIED SURFACE SCIENCE, 2005, 249 (1-4) :71-75
[6]   Study of sol-gel derived porous ZnO photoelectrode for the application of dye-sensitized solar cells [J].
Hossain, M. F. ;
Biswas, S. ;
Shahjahan, M. ;
Takahashi, T. .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2009, 27 (04) :1047-1051
[7]   The effect of sputter-deposited TiO2 passivating layer on the performance of dye-sensitized solar cells based on sol-gel derived photoelectrode [J].
Hossain, M. F. ;
Biswas, S. ;
Takahashi, T. .
THIN SOLID FILMS, 2008, 517 (03) :1294-1300
[8]   Low-temperature solution approach toward highly aligned ZnO nanotip arrays [J].
Hung, CH ;
Whang, WT .
JOURNAL OF CRYSTAL GROWTH, 2004, 268 (1-2) :242-248
[9]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[10]   High electron mobility of epitaxial ZnO thin films on c-plane sapphire grown by multistep pulsed-laser deposition [J].
Kaidashev, EM ;
Lorenz, M ;
von Wenckstern, H ;
Rahm, A ;
Semmelhack, HC ;
Han, KH ;
Benndorf, G ;
Bundesmann, C ;
Hochmuth, H ;
Grundmann, M .
APPLIED PHYSICS LETTERS, 2003, 82 (22) :3901-3903