Nanosecond multiphoton ionisation of jet-cooled ferrocene

被引：8

作者：

Ketkov, SY

Selzle, HL

Schlag, EW

Domrachev, GA

机构：

[1] Univ Munich, Inst Phys & Theoret Chem Technischen, D-85748 Garching, Germany

[2] RAS, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603600, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

ferrocene; multiphoton ionisation; Rydberg states; laser spectroscopy;

D O I：

10.1016/S1387-7003(02)00586-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (CP)(2)Fe+ (CP = eta(5)-C5H5) cations have been obtained in surprisingly high yield by resonance two-colour multiphoton excitation of ferrocene in a jet-cooled molecular beam with tunable nanosecond lasers. The intermediate electronic levels lie in the region of the lowest Rydberg p absorption band. The ion excitation spectrum reveals resolved vibronic structure of the 3d(z)2 --> R4(x,y) transition. The distance between the vibronic components (320 cm(-1)) corresponds to the metal-ligand stretching frequency in the Rydberg state. (C) 2002 Published by Elsevier Science B.V.

引用

页码：909 / 912

页数：4

共 35 条

[1] CAN MOLECULAR ZEKE STATES BE GENERATED BY RYDBERG ELECTRON PICKUP
ALT, C
SCHERZER, WG
SELZLE, HL
SCHLAG, EW
[J]. CHEMICAL PHYSICS LETTERS, 1994, 224 (3-4) : 366 - 370
[2] COOLING OF LARGE AND HEAVY MOLECULES IN SEEDED SUPERSONIC BEAMS
AMIRAV, A
EVEN, U
JORTNER, J
[J]. CHEMICAL PHYSICS, 1980, 51 (1-2) : 31 - 42
[3] ON MOLECULAR STRUCTURE OF FERROCENE FE(C5H5)2
BOHN, RK
HAALAND, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 5 (05) : 470 - +
[4] NORMAL COORDINATE ANALYSIS OF TOTAL FERROCENE COMPLEX
BRUNVOLL, J
CYVIN, SJ
SCHAFER, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 27 (01) : 107 - &
[5] Ultrafast dissociation dynamics of ferrocene and [3]-ferrocenophan
Clara, M
Neusser, HJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (23) : 5577 - 5585
[6] Femtosecond laser mass spectroscopy of ferrocenes: Photochemical stabilization by bridged cyclopentadienyl rings?
Clara, M
Braun, JE
Hellerer, T
Neusser, HJ
[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2000, 203 (1-3) : 71 - 81
[7] ELECTRONIC-STRUCTURE OF VARIOUS FERRICENIUM SYSTEMS AS INFERRED FROM RAMAN, INFRARED, LOW-TEMPERATURE ELECTRONIC ABSORPTION, AND ELECTRON-PARAMAGNETIC RESONANCE MEASUREMENTS
DUGGAN, DM
HENDRICKSON, DN
[J]. INORGANIC CHEMISTRY, 1975, 14 (05) : 955 - 970
[8] Eden J. G., 1992, Photochemical Vapor Deposition
[9] OBSERVATIONS OF MOLECULAR RYDBERG STATE DECAY FOR N=10-200
EVEN, U
LEVINE, RD
BERSOHN, R
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (13) : 3472 - 3477
[10] SPECTROSCOPIC AND MAGNETIC STUDIES OF 3D METALLOCENES
GORDON, KR
WARREN, KD
[J]. INORGANIC CHEMISTRY, 1978, 17 (04) : 987 - 994

← 1 2 3 4 →