Synthesis, molecular structure and reactions of the novel organometallic thioether ligand [WI2(CO){(Me)S(CH2)(2)S(CH2)SMe-S,S'}(eta(2)-PhC(2)Ph)]

被引：4

作者：

Baker, PK

Clark, AI

Coles, SJ

Hursthouse, MB

Richards, RL

机构：

[1] UNIV WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

[2] UNIV WALES COLL CARDIFF,DEPT CHEM,CARDIFF CF1 3TB,S GLAM,WALES

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 518卷 / 1-2期

关键词：

tungsten; sulphur; diphenylacetylene; crystal structure;

D O I：

10.1016/0022-328X(96)06164-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [WI2(CO)(NCMe)(eta(2)-PhC(2)Ph)(2)] with an equimolar quantity of MeS(CH2)(2)S(CH2)(2)SMe in CH2Cl2 at room temperature gave the complex [WI2(CO)((Me)S(CH2)(2)S(CH2)(2)SMe-S, S)(eta(2)-PhC(2)Ph)] (1). The crystal structure of 1 shows the MeS(CH2)(2)S(CH2)(2)SMe ligand attached to the tungsten via two adjacent sulphur atoms, leaving the third sulphur atom uncoordinated. Preliminary studies of the reactions of 1 are also described.

引用

页码：235 / 237

页数：3

共 15 条

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