Four-coordinate iron complexes bearing α-diimine ligands:: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

被引：119
|
作者：
Gibson, VC
O'Reilly, RK
Reed, W
Wass, DF
White, AJP
Williams, DJ
机构：
[1] Univ London Imperial Coll Sci & Technol, Dept Chem, London SW7 2AY, England
[2] BP Chem, Sunbury Res Ctr, Sunbury On Thames TW16 7LN, Middx, England
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 17期
关键词：
D O I：
10.1039/b204510a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.
引用
收藏
页码：1850 / 1851
页数：2
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