Four-coordinate iron complexes bearing α-diimine ligands:: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

被引：119

作者：

Gibson, VC

O'Reilly, RK

Reed, W

Wass, DF

White, AJP

Williams, DJ

机构：

[1] Univ London Imperial Coll Sci & Technol, Dept Chem, London SW7 2AY, England

[2] BP Chem, Sunbury Res Ctr, Sunbury On Thames TW16 7LN, Middx, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 17期

关键词：

D O I：

10.1039/b204510a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.

引用

页码：1850 / 1851

页数：2

共 45 条

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