Four-coordinate iron complexes bearing α-diimine ligands:: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

被引：119
作者：
Gibson, VC
O'Reilly, RK
Reed, W
Wass, DF
White, AJP
Williams, DJ
机构：
[1] Univ London Imperial Coll Sci & Technol, Dept Chem, London SW7 2AY, England
[2] BP Chem, Sunbury Res Ctr, Sunbury On Thames TW16 7LN, Middx, England
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 17期
关键词：
D O I：
10.1039/b204510a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.
引用
收藏
页码：1850 / 1851
页数：2
相关论文
共 25 条
  • [1] Iron(II) chloride complex for living radical polymerization of methyl methacrylate
    Ando, T
    Kamigaito, M
    Sawamoto, M
    [J]. MACROMOLECULES, 1997, 30 (16) : 4507 - 4510
  • [2] Comparing structures and reactivity in analogous Fe and Ru complexes.: (iPr-DAB)Fe(CO)2I2 and (iPr-DAB)FeI2:: a perfectly reversible CO-carrier system.: (R-DAB = N,N′-R2-1,4-diara-1,3-butadiene)
    Breuer, J
    Frühauf, HW
    Smeets, WJJ
    Spek, AL
    [J]. INORGANICA CHIMICA ACTA, 1999, 291 (1-2) : 438 - 447
  • [3] Novel olefin polymerization catalysts based on iron and cobalt
    Britovsek, GJP
    Gibson, VC
    Kimberley, BS
    Maddox, PJ
    McTavish, SJ
    Solan, GA
    White, AJP
    Williams, DJ
    [J]. CHEMICAL COMMUNICATIONS, 1998, (07) : 849 - 850
  • [4] Iron and cobalt ethylene polymerization catalysts bearing 2,6-bis(imino)pyridyl ligands:: Synthesis, structures, and polymerization studies
    Britovsek, GJP
    Bruce, M
    Gibson, VC
    Kimberley, BS
    Maddox, PJ
    Mastroianni, S
    McTavish, SJ
    Redshaw, C
    Solan, GA
    Strömberg, S
    White, AJP
    Williams, DJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) : 8728 - 8740
  • [5] 4-methoxypyridine N-oxide: A new regulator for the controlled free radical polymerization of methyl methacrylate
    Detrembleur, C
    Lecomte, P
    Caille, JR
    Creutz, S
    Dubois, P
    Teyssie, P
    Jerome, R
    [J]. MACROMOLECULES, 1998, 31 (20) : 7115 - 7117
  • [6] Göbelt B, 2000, MACROMOL CHEM PHYSIC, V201, P1619, DOI 10.1002/1521-3935(20000901)201:14<1619::AID-MACP1619>3.0.CO
  • [7] 2-O
  • [8] Controlled radical polymerization of methacrylic monomers in the presence of a bis(ortho-chelated) arylnickel(II) complex and different activated alkyl halides
    Granel, C
    Dubois, P
    Jerome, R
    Teyssie, P
    [J]. MACROMOLECULES, 1996, 29 (27) : 8576 - 8582
  • [9] POLYMERIZATION OF METHYL-METHACRYLATE WITH THE CARBON-TETRACHLORIDE DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) METHYLALUMINUM BIS(2,6-DI-TERT-BUTYLPHENOXIDE) INITIATING SYSTEM - POSSIBILITY OF LIVING RADICAL POLYMERIZATION
    KATO, M
    KAMIGAITO, M
    SAWAMOTO, M
    HIGASHIMURA, T
    [J]. MACROMOLECULES, 1995, 28 (05) : 1721 - 1723
  • [10] FeCp(CO)2I:: A phosphine-free half-metallocene-type iron(II) catalyst for living radical polymerization of styrene
    Kotani, Y
    Kamigaito, M
    Sawamoto, M
    [J]. MACROMOLECULES, 1999, 32 (20) : 6877 - 6880
123