Optimized Nb-Based Zeolites as Catalysts for the Synthesis of Succinic Acid and FDCA

被引:17
作者
El Fergani, Magdi [1 ]
Candu, Natalia [1 ]
Tudorache, Madalina [1 ]
Granger, Pascal [2 ]
Parvulescu, Vasile, I [1 ]
Coman, Simona M. [1 ]
机构
[1] Univ Bucharest, Fac Chem, Dept Organ Chem Biochem & Catalysis, Bdul Regina Elisabeta 4-12, Bucharest 030016, Romania
[2] Univ Lille, Univ Artois, UCCS Unite Catalyse & Chim Solide, CNRS,Cent Lille,ENSCL,UMR 8181, F-59000 Lille, France
关键词
zeolite; silicalite; niobium oxide; HMF; glucose; wet oxidation; organic peroxides; succinic acid; FDCA; NIOBIUM OXIDE CATALYSTS; MOLECULAR-SIEVES; CHEMICAL ROUTES; SILICA; OXIDATION; BIOMASS; SITES; TRANSFORMATION; EPOXIDATION; STABILITY;
D O I
10.3390/molecules25214885
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Nb(0.05 moles%)-zeolites prepared via a post synthesis methodology (BEA, Y, ZSM-5), or a direct sol-gel method (Silicalite-1) were investigated in the hydroxymethylfurfural (HMF) oxidation by both molecular oxygen, in aqueous phase, and organic peroxides, in acetonitrile. The catalysts prepared through the post synthesis methodology (i.e., Nb-Y5, Nb-ZSM25, Nb-Y30, Nb-BEA12, and Nb-BEA18) displayed a mono-modal mesoporosity and contain residual framework Al-acid sites, extra framework isolated Nb(V)O-H and Nb2O5 pore-encapsulated clusters, while Nb-Sil-1, prepared through a direct synthesis procedure, displayed a bimodal micro-mesoporosity and contains only -Nb=O species. These modified zeolites behave as efficient catalysts in both HMF/glucose wet oxidation to succinic acid (SA) and HMF oxidation with organic peroxides to the 2,5-furandicarboxylic acid (FDCA). The catalytic behavior of these catalysts, in terms of conversion and especially the selectivity, mainly depended on the base/acid sites ratio. Thus, the HMF/glucose wet oxidation occurred with a total conversion and a selectivity to SA of 37.7% (from HMF) or 69.1% (from glucose) on the Nb-Y5 catalyst, i.e., the one with the lowest base/acid sites ratio. On the contrary, the catalysts with the highest base/acid sites ratio, i.e., Nb-ZSM25 and Nb-Sil-1, afforded a high catalytic efficiency in HMF oxidation with organic peroxides, in which FDCA was produced with selectivities of 61.3-63.8% for an HMF conversion of 96.7-99.0%.
引用
收藏
页数:16
相关论文
共 50 条
[21]   Metal ion-exchanged zeolites as highly active solid acid catalysts for the green synthesis of glycerol carbonate from glycerol [J].
Marakatti, Vijaykumar S. ;
Halgeri, Anand B. .
RSC ADVANCES, 2015, 5 (19) :14286-14293
[22]   Hydrothermal synthesis of boron-free Zr-MWW and Sn-MWW zeolites as robust Lewis acid catalysts [J].
Zhu, Zhiguo ;
Guan, Yejun ;
Ma, Haikuo ;
Xu, Hao ;
Jiang, Jin-gang ;
Lu, Hongying ;
Wu, Peng .
CHEMICAL COMMUNICATIONS, 2020, 56 (34) :4696-4699
[23]   New adsorbents and acid-base catalysts based on binder-free granulated zeolites of LTA and FAU types [J].
B. I. Kutepov ;
O. S. Travkina ;
I. N. Pavlova ;
A. N. Khazinova ;
N. G. Grigor’eva ;
M. L. Pavlov .
Russian Journal of Applied Chemistry, 2015, 88 :65-71
[24]   Design and Synthesis of Mesoporous Polymer-Based Solid Acid Catalysts with Excellent Hydrophobicity and Extraordinary Catalytic Activity [J].
Liu, Fujian ;
Kong, Weiping ;
Qi, Chenze ;
Zhu, Longfeng ;
Xiao, Feng-Shou .
ACS CATALYSIS, 2012, 2 (04) :565-572
[25]   Development of catalysts based on pentasil-type zeolites for selective synthesis of lower olefins from methanol and dimethyl ether [J].
A. V. Abramova .
Catalysis in Industry, 2009, 1 (4) :267-277
[26]   Aqueous-Phase Hydrogenation of Biomass-Based Succinic Acid to 1,4-Butanediol Over Supported Bimetallic Catalysts [J].
Doan Pham Minh ;
Michèle Besson ;
Catherine Pinel ;
Patrick Fuertes ;
Carole Petitjean .
Topics in Catalysis, 2010, 53 :1270-1273
[27]   Aqueous-Phase Hydrogenation of Biomass-Based Succinic Acid to 1,4-Butanediol Over Supported Bimetallic Catalysts [J].
Minh, Doan Pham ;
Besson, Michele ;
Pinel, Catherine ;
Fuertes, Patrick ;
Petitjean, Carole .
TOPICS IN CATALYSIS, 2010, 53 (15-18) :1270-1273
[28]   Nb(Ta)-based solid acid modified Pt/CNTs catalysts for hydrodeoxygenation of lignin-derived compounds [J].
Guan, Weixiang ;
Chen, Xiao ;
Li, Chuang ;
Zhang, Jie ;
Tsang, Chi-Wing ;
Hu, Haoquan ;
Li, Shaojie ;
Liang, Changhai .
MOLECULAR CATALYSIS, 2019, 467 :61-69
[29]   Novel membrane-based biotechnological alternative process for succinic acid production and chemical synthesis of bio-based poly (butylene succinate) [J].
Wang, Caixia ;
Ming, Wei ;
Yan, Daojiang ;
Zhang, Congcong ;
Yang, Maohua ;
Liu, Yilan ;
Zhang, Yu ;
Guo, Baohua ;
Wan, Yinhua ;
Xing, Jianmin .
BIORESOURCE TECHNOLOGY, 2014, 156 :6-13
[30]   Synthesis of Porous Organic Polymer-Based Solid-Acid Catalysts for 5-Hydroxymethylfurfural Production from Fructose [J].
Sebati, Wilhemina ;
Ray, Suprakas Sinha ;
Moutloali, Richard .
CATALYSTS, 2019, 9 (08)