Synthesis of Nitriles from Aerobic Oxidation of Amines Catalyzed by Ruthenium Supported on Activated Carbon

被引：9
作者：
Niu, Baoqiang [1 ]
Lu, Fei [1 ]
Zhang, Hong-Yu [1 ]
Zhang, Yuecheng [1 ]
Zhao, Jiquan [1 ]
机构：
[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 03期
基金：
高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词：
Aerobic oxidation; Nitrile; Ruthenium; C-H BONDS; EFFICIENT CATALYST; COMPLEX; N; N-DIMETHYLFORMAMIDE; CONVERSION; CYANATION; HYDROXIDE; ALCOHOLS; CYSTEINE; OXIDANT;
D O I：
10.1246/cl.160989
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nitriles were synthesized from the aerobic oxidation of amines over commercially available catalysts, which were activated carbon-supported ruthenium catalysts (Ru/AC). The 5% Ru/AC catalyst can tolerate a wide range of substrates, such as aromatic, aliphatic, and heterocyclic amines, and afford the target nitriles in good-to-excellent yields. The 5% Ru/AC catalyst was easily recovered and no ruthenium leaking took place in the catalytic run.
引用
收藏
页码：330 / 333
页数：4
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