Chemistry of difluorocarbene adducts:: Stereospecific synthesis of conjugated fluoroolefins and 1,3-azabutadienes from gem-difluorocyclopropenyl ketones

被引:16
作者
Cheng, Zhan-Ling [1 ]
Chen, Qing-Yun [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
基金
中国国家自然科学基金;
关键词
difluorocarbene; gem-difluorocyclopropenyl ketone; ring opening reaction;
D O I
10.1016/j.jfluchem.2006.03.020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of gem-difluorocyclopropenyl ketones with malonate anion, amine gave stereospecifically conjugated fluoroolefins and azabutadienes, respectively. (c) 2006 Elsevier B.V All rights reserved.
引用
收藏
页码:894 / 900
页数:7
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