Phase transition and improved electrical performance of Ba0.85Ca0.15Zr0.1Ti0.9O3-Ca0.28Ba0.72Nb2O6 ceramics with high Curie temperature

被引：33
作者：
Chao, Xiaolian [1 ]
Wang, Juanjuan [2 ]
Liang, Pengfei [1 ]
Zhang, Ting [1 ]
Wei, Lingling [1 ]
Yang, Zupei [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Mat Sci & Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China
[2] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Shaanxi, Peoples R China
来源：
MATERIALS & DESIGN | 2016年 / 89卷
基金：
美国国家科学基金会;
关键词：
Electrical properties; Piezoelectricity; Ba0.85Ca0.15Zr0.1Ti0.9O3; Curie temperature; LEAD-FREE CERAMICS; PIEZOELECTRIC PROPERTIES; FERROELECTRIC PROPERTIES; MICROSTRUCTURE; CA;
D O I：
10.1016/j.matdes.2015.10.014
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
To enhance the electrical properties and Curie temperature of lead-free piezoelectric materials, polycrystalline Ba0.83Ca0.15Zr0.1Ti0.9O3-xCa(0.28)Ba(0.72)Nb(2)O(6) (BCZT-xCBN) ceramics were synthesized by solid-state reaction. X-ray diffraction analysis of the ceramics revealed that the crystal structure changed from orthorhombic to tetragonal, with an increase in CBN content. The Curie temperature was improved from 91 degrees C to 98 degrees C and favorable electrical properties (d(33) similar to 590 pC/N, k(p) similar to 0.46) were obtained for the BCZT-0.2 mol% CBN ceramics, along with high remnant polarization (P-r = 12.5 mu C/cm(2)), and a low coercive field strength (E-c = 1.5 kV/cm). The ceramics also exhibited good dielectric temperature stability over a wide temperature range. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：465 / 469
页数：5
相关论文
共 28 条
  • [1] (Ba,Ca)(Zr,Ti)O3 lead-free piezoelectric ceramics-The critical role of processing on properties
    Bai, Yang
    Matousek, Ales
    Tofel, Pavel
    Bijalwan, Vijay
    Nan, Bo
    Hughes, Hana
    Button, Tim W.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (13) : 3445 - 3456
  • [2] Chemical Synthesis, Sintering and Piezoelectric Properties of Ba0.85Ca0.15 Zr0.1Ti0.9O3 Lead-Free Ceramics
    Castkova, Klara
    Maca, Karel
    Cihlar, Jaroslav
    Hughes, Hana
    Matousek, Ales
    Tofel, Pavel
    Bai, Yang
    Button, Tim W.
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (08) : 2373 - 2380
  • [3] Ba(Cu0.5W0.5)O3-induced sinterability, electrical and mechanical properties of (Ba0.85Ca0.15Ti0.90Zr0.10)O3 ceramics sintered at low temperature
    Chao, Xiaolian
    Wang, ZhongMing
    Tian, Ye
    Zhou, Yanzhao
    Yang, Zupei
    [J]. MATERIALS RESEARCH BULLETIN, 2015, 66 : 16 - 25
  • [4] Piezoelectric properties of [Li0.03(K0.48Na0.52)0.97](Nb0.97Sb0.03)O3-(Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 lead-free piezoelectric ceramics
    Chen, Xiaoyu
    Wu, Jiagang
    Cheng, Xiaojing
    Wu, Bo
    Wu, Wenjuan
    Xiao, Dingquan
    Zhu, Jianguo
    [J]. CURRENT APPLIED PHYSICS, 2012, 12 (03) : 752 - 754
  • [5] Dielectric Properties and Impedance Analysis of K0.5Na0.5NbO3-Ba2NaNb5O15 Ceramics with Good Dielectric Temperature Stability
    Chen, Xiuli
    Wang, Yiliang
    Chen, Jie
    Zhou, Huanfu
    Fang, Liang
    Liu, Laijun
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (11) : 3489 - 3493
  • [6] Elastic response of (1-x)Ba(Ti0.8Zr0.2)O3 - x(Ba0.7Ca0.3)TiO3 (x=0.45-0.55) and the role of the intermediate orthorhombic phase in enhancing the piezoelectric coupling
    Cordero, F.
    Craciun, F.
    Dinescu, M.
    Scarisoreanu, N.
    Galassi, C.
    Schranz, W.
    Soprunyuk, V.
    [J]. APPLIED PHYSICS LETTERS, 2014, 105 (23)
  • [7] Enhanced d33 value of Bi0.5Na0.5TiO3-(Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 lead-free ceramics
    Gou, Qian
    Wu, Jiagang
    Li, Anqi
    Wu, Bo
    Xiao, Dingquan
    Zhu, Jianguo
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 521 : 4 - 7
  • [8] Phase formation, dielectric and ferroelectric properties of CaxBa1-xNb2O6 ceramics
    Han, Xiaokun
    Wei, Lingling
    Yang, Zupei
    Zhang, Ting
    [J]. CERAMICS INTERNATIONAL, 2013, 39 (05) : 4853 - 4860
  • [9] Effect of BaTiO3 addition on the microstructure and relaxor ferroelectric properties of Sr0.7Ba0.3Nb2O6 ceramics
    Li, Jinglei
    Pu, Yongping
    Wang, Zhuo
    Dai, Jie
    [J]. CERAMICS INTERNATIONAL, 2012, 38 (08) : 6699 - 6704
  • [10] Large Piezoelectric Effect in Pb-Free Ceramics
    Liu, Wenfeng
    Ren, Xiaobing
    [J]. PHYSICAL REVIEW LETTERS, 2009, 103 (25)
123