Copper-catalysed oxidative C-H/C-H coupling between olefins and simple ethers

被引：152

作者：

Liu, Dong ^{[1
]}

Liu, Chao ^{[1
]}

Li, Heng ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 27期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

ASYMMETRIC TOTAL-SYNTHESIS; BOND FORMATION; DIRECT FUNCTIONALIZATION; BENZYL ETHERS; ALCOHOLS; TETRAHYDROFURAN; EFFICIENT; SECONDARY; ADJACENT; ALKENES;

D O I：

10.1039/c4cc00867g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first copper-catalysed oxidative alkenylation of simple ethers to construct allylic ethers was successfully achieved. Different substituted olefins and simple ethers could be cross-coupled well to generate the corresponding alkenylation products. Notably, open-chain ethers were also found to be efficient coupling partners in this reaction. This reaction is likely to proceed via a radical process.

引用

页码：3623 / 3626

页数：4

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