Desymmetrization of substituted 1,3-diketones: A formal synthesis of (+)-stemoamide

被引：18

作者：

Bogliotti, Nicolas ^{[1
]}

Dalko, Peter I. ^{[1
]}

Cossy, Janine ^{[1
]}

机构：

[1] ESPCI, CNRS, Chim Organ Lab, F-75231 Paris 05, France

来源：

SYNLETT | 2006年 / 16期

关键词：

reduction; desymmetrization; alkaloids; stereoselective synthesis;

D O I：

10.1055/s-2006-951475

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A reductive desymmetrization of a gamma-1,3-diketoester was used as the key step to control the C8, C9 and C9a stereocenters off (+)-stemoamide.

引用

页码：2664 / 2666

页数：3

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