Desymmetrization of substituted 1,3-diketones: A formal synthesis of (+)-stemoamide

被引：18
作者：
Bogliotti, Nicolas [1 ]
Dalko, Peter I. [1 ]
Cossy, Janine [1 ]
机构：
[1] ESPCI, CNRS, Chim Organ Lab, F-75231 Paris 05, France
来源：
SYNLETT | 2006年 / 16期
关键词：
reduction; desymmetrization; alkaloids; stereoselective synthesis;
D O I：
10.1055/s-2006-951475
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A reductive desymmetrization of a gamma-1,3-diketoester was used as the key step to control the C8, C9 and C9a stereocenters off (+)-stemoamide.
引用
收藏
页码：2664 / 2666
页数：3
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