Thieno-Pyrrole-Fused 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene-Fullerene Dyads: Utilization of Near-Infrared Sensitizers for Ultrafast Charge Separation in Donor-Acceptor Systems

被引：58
作者：
Bandi, Venugopal [1 ]
Das, Sushanta K. [1 ]
Awuah, Samuel G. [2 ]
You, Youngjae [2 ]
D'Souza, Francis [1 ]
机构：
[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA
[2] Univ Oklahoma, Hlth Sci Ctr, Dept Pharmaceut Sci, Oklahoma City, OK 73117 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 21期
基金：
美国国家科学基金会;
关键词：
ELECTRON-TRANSFER PROCESSES; BODIPY DYES; PHOTODYNAMIC THERAPY; FULLERENE; CHEMISTRY; C-60;
D O I：
10.1021/ja503015f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Donor acceptor dyads featuring near-IR sensitizers derived from thieno-pyrrole-fused BODIPY (abbreviated as SBDPiR) and fullerene, C-60 have been newly synthesized and characterized. Occurrence of ultrafast photoinduced electron transfer (PET) leading to the formation of charge-separated state in these dyads, capable of harvesting light energy from the near-IR region, is established from femtosecond transient absorption studies.
引用
收藏
页码：7571 / 7574
页数：4
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