Novel crystal modification of fac-Triamminetrinitrorhodium(III) -: β-fac-[Rh(No2)3(NH3)3]

被引：3

作者：

Gromilov, S. A. ^{[1
]}

Korenev, S. V. ^{[1
]}

Baidina, I. A. ^{[1
]}

Khranenko, S. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 46卷 / 04期

关键词：

rhodium; powder X-ray diffraction; single crystal X-ray diffraction; crystal chemistry;

D O I：

10.1007/s10947-006-0191-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The paper describes the preparation techniques for beta-fac-[Rh(NO2)(3)(NH3)(3)]. The complex crystallizes as colorless prisms belonging to the monoclinic crystal system. Crystal data: a = 6.6338(2) angstrom, b = 11.062:7(3) angstrom, c=11.5314(3)angstrom; beta =96.608(1)degrees, V=840.64(4)angstrom(3), space group P2(1)/n, Z=4, d(calc)= 2.308 g/cm(3). The structure is molecular and contains neutral complex molecules having the fac configuration. Crystal chemical analysis of the complex in comparison to alpha-fac-[Rh(NO2)(3)(NH3)(3)] is performed. Keywords: rhodium, powder X-ray diffraction, single crystal X-ray diffraction, crystal chemistry.

引用

页码：719 / 724

页数：6