Base free, one-pot synthesis of lactic acid from glycerol using a bifunctional Pt/Sn-MFI catalyst

被引：108
作者：
Cho, Hong Je [1 ]
Chang, Chun-Chih [1 ]
Fan, Wei [1 ]
机构：
[1] Univ Massachusetts, Dept Chem Engn, Amherst, MA 01003 USA
来源：
GREEN CHEMISTRY | 2014年 / 16卷 / 07期
关键词：
FREE AQUEOUS-SOLUTION; SELECTIVE OXIDATION; LEWIS-ACID; CELLULOSIC SUGARS; AEROBIC OXIDATION; FUEL PRODUCTION; SN-BETA; CONVERSION; CHEMICALS; ZEOLITES;
D O I：
10.1039/c4gc00723a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Under base free and mild reaction conditions, 80.5% selectivity of lactic acid (LA) was achieved at 89.8% conversion of glycerol using a bifunctional Pt/Sn-MFI catalyst. In the tandem reaction pathway, selective oxidation of glycerol to glyceraldehyde (GLA) and dihydroxyacetone (DHA) was cascaded with Lewis acid catalyzed isomerization of GLA/DHA into LA.
引用
收藏
页码：3428 / 3433
页数：6
相关论文
共 50 条
  • [41] One-Pot Cascade Synthesis of 2-Cyanoacrylamides via Sn-Catalyzed Acetic Acid Free Selective Monohydration of Dinitrile
    Shaikh, Taufeekaslam M. Y.
    Mulla, Shafeek A. R.
    [J]. CHEMISTRYSELECT, 2018, 3 (12): : 3534 - 3538
  • [42] One-pot synthesis of 5-hydroxymethylfurfural from carbohydrates using an inexpensive FePO4 catalyst
    Yang, Li
    Yan, Xiaopei
    Xu, Siquan
    Chen, Hao
    Xia, Haian
    Zuo, Songlin
    [J]. RSC ADVANCES, 2015, 5 (26): : 19900 - 19906
  • [43] One-pot synthesis of acrylic acid from glycerol over SBA-15 supported heteropoly acid catalysts: Influence of mesoporosity and acidity
    Ahmad, Muhammad Yusri
    Saleh, Syamima Nasrin Mohamed
    Abdullah, Ahmad Zuhairi
    [J]. APPLIED CATALYSIS A-GENERAL, 2024, 670
  • [44] Efficient One-Pot Synthesis of 5-(Ethoxymethyl)furfural from Fructose Catalyzed by a Novel Solid Catalyst
    Bing, Liu
    Zhang, Zehui
    Deng, Kejian
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (47) : 15331 - 15336
  • [45] One-pot catalytic production of 1, 3-propanediol and γ-valerolactone from glycerol and levulinic acid
    Wu, Zhijie
    Zhang, Min
    Yao, Yirong
    Wang, Jingtuo
    Wang, Danhong
    Zhang, Minghui
    Li, Yongfeng
    [J]. CATALYSIS TODAY, 2018, 302 : 217 - 226
  • [46] Synthesis of glycerol carbonate from glycerol and dialkyl carbonates using hydrotalcite as a reusable heterogeneous base catalyst
    Takagaki, Atsushi
    Iwatani, Ken
    Nishimura, Shun
    Ebitani, Kohki
    [J]. GREEN CHEMISTRY, 2010, 12 (04) : 578 - 581
  • [47] P-Dodecylbenzenesulfonic Acid: A Highly Efficient Catalyst for One-Pot Synthesis of -Aminophosphonates in Aqueous Media
    Movassagh, Barahman
    Alapour, Saba
    [J]. HETEROATOM CHEMISTRY, 2013, 24 (03) : 174 - 178
  • [48] One-step synthesis of pyruvic acid from glycerol oxidation over Pb promoted Pt/activated carbon catalysts
    Zhang, Chen
    Wang, Tao
    Ding, Yunjie
    [J]. CHINESE JOURNAL OF CATALYSIS, 2017, 38 (05) : 928 - 938
  • [49] One-pot synthesis of gluconic acid from biomass-derived levoglucosan using a Au/Cs2.5H0.5PW12O40 catalyst
    Wan, Yan
    Zhang, Lina
    Chen, Yeyun
    Lin, Jinhan
    Hu, Wenda
    Wang, Shuai
    Lin, Jingdong
    Wan, Shaolong
    Wang, Yong
    [J]. GREEN CHEMISTRY, 2019, 21 (23) : 6318 - 6325
  • [50] Solvent- and base-free synthesis of wax esters from fatty acid methyl esters by consecutive one-pot, two-step catalysis
    Nguyen, D. H.
    Raffa, G.
    Morin, Y.
    Desset, S.
    Capet, F.
    Nardello-Rataj, V.
    Dumeignil, F.
    Gauvin, R. M.
    [J]. GREEN CHEMISTRY, 2017, 19 (23) : 5665 - 5673
12345