Proton-conductivity-enhancing Ionic Liquid Consisting of Guanidine and Excess Trifluoromethanesulfonic Acid

被引:8
作者
Kuroha, Michiaki [1 ]
Gotoh, Hiroaki [1 ]
Miran, Muhammed Shah [1 ]
Yasuda, Tomohiro [1 ]
Watanabe, Masayoshi [1 ]
Sakakibara, Kazuhisa [1 ]
机构
[1] Yokohama Natl Univ, Dept Adv Mat Chem, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
关键词
PHYSICOCHEMICAL PROPERTIES; HYDROGEN-BONDS; BASE; ELECTROLYTES; CONDUCTORS; MECHANISM;
D O I
10.1246/cl.131177
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Proton-conductivity-enhancing ionic liquid (IL) has been prepared from 1,1,3,3-tetramethylguanidine (TMG) and excess trifluoromethanesulfonic acid (TfOH). The fast mobile nature of conductive protons has been characterized by NMR, IR spectroscopy and B3LYP/6-31G* calculations.
引用
收藏
页码:649 / 651
页数:3
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