Supramolecular templating of hierarchically porous metal-organic frameworks

被引：249

作者：

Bradshaw, Darren ^{[1
]}

El-Hankari, Samir ^{[1
]}

Lupica-Spagnolo, Lucia ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 16期

基金：

欧洲研究理事会;

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORK-8; COORDINATION POLYMER; EFFICIENT; ROUTES; SIZE;

D O I：

10.1039/c4cs00127c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review summarises recent advances in the direct supramolecular templating of metal-organic frameworks (MOFs) with hierarchical porosity across the micro- and mesoporous regimes. These are set against the important synthetic considerations that need to be addressed to ensure that strong interactions between the MOF precursors and a stable template assembly allow the highest chance of success. The article is grouped by template type and each category is illustrated with key examples and, where reported, an evaluation of their enhanced properties arising from the hierarchical structuring of the porous networks.

引用

页码：5431 / 5443

页数：13

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