Solvothermally derived Me2(H2O)4(5SSA)3•DMF and Me2(H2O)4 (4NSA)2•DMF: Application as Biginelli reaction catalysts

被引：0

作者：

Laurikenas, Andrius ^{[1
]}

Yalcin, Fatma ^{[2
]}

Zilinskas, Robertas ^{[1
]}

Morkan, Ayse Uztetik ^{[2
]}

Zilinskas, Albinas ^{[1
]}

Morkan, Izzet Amour ^{[2
]}

Kareiva, Aivaras ^{[1
]}

机构：

[1] Vilnius Univ, Inst Chem, 24 Naugarduko St, LT-03225 Vilnius, Lithuania

[2] Abant Izzet Baysal Univ, Inst Nat Sci, Dept Chem, TR-14030 Bolu, Turkey

来源：

CHEMIJA | 2019年 / 30卷 / 02期

关键词：

solvothermal synthesis; hybrid organic-inorganic compounds; Biginelli reaction; catalytic activity; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; CHAINS SYNTHESES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvothermal synthesis between Me(NO3)(x)center dot yH(2)O (me(x+) = Fe3+, Ni2+, M2+, Co2+, Cu2+) and respectively 4-nitrosalycilic (4NSA) and 5-sulfosalicylic (5SSA) acids produced hybrid organic-inorganic compounds composed of me- ions and organic fragments which include three different functional groups, carboxylic, hydroxyl and sulfonic, each coordinated to the Mex+ ions. The phase and chemical composition, microstructure and properties of Me-2(H2O)(4)(5SSA)3 center dot DMF and Me-2(H2O)(4)(4NSA)(2)center dot DMF (DMF - dimethylformamide) hybrid compounds were evaluated and discussed. The synthesised materials were characterised by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) spectroscopy. The catalytic properties of the obtained compounds were also investigated.

引用

页码：89 / 97

页数：9

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