Tris(2,2′-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions

被引：12

作者：

Setifi, Zouaoui ^{[1
,2
]}

Setifi, Fatima ^{[3
]}

Boughzala, Habib ^{[4
]}

Beghidja, Adel ^{[2
]}

Glidewell, Christopher ^{[5
]}

机构：

[1] Fac Technol, Dept Technol, Skikda 21000, Algeria

[2] Univ Constantine 1, Unite Rech Chim Environm & Mol Struct Chems, Constantine 25000, Algeria

[3] Univ Ferhat Abbas Setif 1, LCIMN, Setif 19000, Algeria

[4] Univ Tunis El Manar, Fac Sci Tunis, Lab Mat & Cristallochim, Manar Ii Tunis 2092, Tunisia

[5] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2014年 / 70卷

关键词：

crystal structure; hydrogen bonding; tris(2,2 '-bipyridine)iron(II); 1,1,3,3-tetracyano-2-ethoxypropenide; interpenetrating chiral frameworks; polynitrile ligands; spin crossover (SCO) phenomenon; SPIN-CROSSOVER; PHENYLPHOSPHONIC ACID; COMPLEXES; 4,4'-SULFONYLDIPHENOL; 4,4'-THIODIPHENOL; CHEMISTRY; ADDUCTS; SALTS; BLOCK; SHEET;

D O I：

10.1107/S2053229614008092

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [Fe(C10H8N2)(3)](C9H5N4O)(2)center dot 2H(2)O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H center dot center dot center dot N hydrogen bonds to form C-2(2)(8) chains, and these chains are linked by the cations via C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.

引用

页码：465 / U174

页数：11

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