Tris(2,2′-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate: chiral hydrogen-bonded frameworks interpenetrate in three dimensions

被引：12
|
作者：
Setifi, Zouaoui [1 ,2 ]
Setifi, Fatima [3 ]
Boughzala, Habib [4 ]
Beghidja, Adel [2 ]
Glidewell, Christopher [5 ]
机构：
[1] Fac Technol, Dept Technol, Skikda 21000, Algeria
[2] Univ Constantine 1, Unite Rech Chim Environm & Mol Struct Chems, Constantine 25000, Algeria
[3] Univ Ferhat Abbas Setif 1, LCIMN, Setif 19000, Algeria
[4] Univ Tunis El Manar, Fac Sci Tunis, Lab Mat & Cristallochim, Manar Ii Tunis 2092, Tunisia
[5] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2014年 / 70卷
关键词：
crystal structure; hydrogen bonding; tris(2,2 '-bipyridine)iron(II); 1,1,3,3-tetracyano-2-ethoxypropenide; interpenetrating chiral frameworks; polynitrile ligands; spin crossover (SCO) phenomenon; SPIN-CROSSOVER; PHENYLPHOSPHONIC ACID; COMPLEXES; 4,4'-SULFONYLDIPHENOL; 4,4'-THIODIPHENOL; CHEMISTRY; ADDUCTS; SALTS; BLOCK; SHEET;
D O I：
10.1107/S2053229614008092
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [Fe(C10H8N2)(3)](C9H5N4O)(2)center dot 2H(2)O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H center dot center dot center dot N hydrogen bonds to form C-2(2)(8) chains, and these chains are linked by the cations via C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.
引用
收藏
页码：465 / U174
页数：11
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