Studying the frequency dispersion of the dielectric permeability of electrolyte solutions

被引:3
作者
Odinaev, S. [1 ]
Makhmadbegov, R. S. [2 ]
机构
[1] Tajikistan Acad Sci, Dushanbe 734025, Tajikistan
[2] Tajik Natl Univ, Dushanbe 734025, Tajikistan
关键词
specific conductivity coefficient; dielectric permeability coefficient; dielectric losses; intermolecular interaction potential; radial distribution function; friction coefficient; relaxation times; AQUEOUS-SOLUTIONS; RELAXATION; SPECTROSCOPY;
D O I
10.1134/S0036024416010210
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Analytical equations for coefficients of dielectric permeability epsilon(1)(omega) and dielectric losses epsilon(2)(omega) of electrolyte solutions are obtained, based on the relationship between complex dielectric permeability and specific conductivity coefficients. The region of frequency dispersion is considered for dynamic dielectric permeability coefficient epsilon(1)(omega) of an aqueous NaCl solution. Friction coefficients beta (a) and beta (b) , relaxation times tau (a) , tau (b) , and tau (ab) , and dielectric permeability coefficient epsilon(1)(omega) are numerically calculated for selected intermolecular interaction potentials and equilibrium radial distribution functions over a wide range of variation in density rho, concentration c, temperature T, and frequencies omega. The theoretically calculated results for epsilon(1)(omega) are found to be in quantitative agreement with experimental data.
引用
收藏
页码:89 / 94
页数:6
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