Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions

被引：39

作者：

Runde, Wolfgang ^{[1
]}

Brodnax, Lia F. ^{[2
]}

Goff, George ^{[1
]}

Bean, Amanda C. ^{[2
]}

Scott, Brian L. ^{[3
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

[2] Los Alamos Natl Lab, Plutonium Mfg & Technol Div, Los Alamos, NM 87545 USA

[3] Los Alamos Natl Lab, Mat Phys & Applicat Div, Los Alamos, NM 87545 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

POWDER CRYSTALLOGRAPHIC DATA; THERMAL-DECOMPOSITION; SINGLE-CRYSTAL; MIXED SITE; COMPLEXES; CARBONATE; COORDINATION; FRAMEWORK; NETWORK; SERIES;

D O I：

10.1021/ic900344u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of hydrated oxalates of Pu(III), Pu-2(C2O4)(3)(H2O)6 center dot 3H(2)O and Pu(IV), KPu(C2O4)(2)-(OH)center dot 2.5H(2)O, were synthesized under moderate hydrothermal conditions and characterized by single crystal X-ray diffraction studies. These compounds are the first plutonium (III) or (IV) oxalate compounds to be structurally characterized via single crystal X-ray diffraction studies.

引用

页码：5967 / 5972

页数：6

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