Dehydration of 2,3-butanediol into 3-buten-2-ol catalyzed by ZrO2

被引：64

作者：

Duan, Hailing ^{[1
]}

Sun, Daolai ^{[1
]}

Yamada, Yasuhiro ^{[1
]}

Sato, Satoshi ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Engn, Inage Ku, Chiba 2638522, Japan

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 48卷

关键词：

2,3-Butanediol; Dehydration; 3-Buten-2-ol; Monoclinic ZrO2; EARTH-OXIDE CATALYSTS; SELECTIVE DEHYDRATION; 1,4-BUTANEDIOL; CEO2; SURFACE; ALCOHOLS; DIOLS; CERIA;

D O I：

10.1016/j.catcom.2014.01.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vapor-phase catalytic dehydration of 2,3-butanediol was investigated over metal oxides such as CeO2, La2O3, Yb(2)O3, ZrO2, Al2O3, TiO2, ZnO, Fe2O3, NiO, and Cr2O3. In the dehydration of 2,3-butanedio13-buten-2-ol was preferentially produced over monoclinic ZrO2 along with major by-products such as butanone and 3-hydroxy-2-butanone. Over ZrO2 calcined at 900 degrees C, 3-buten-2-ol was produced with a maximum selectivity of 59.0% at 300 degrees C without producing 1,3-butadiene. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：1 / 4

页数：4

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