Dehydration of 2,3-butanediol into 3-buten-2-ol catalyzed by ZrO2

被引：64
作者：
Duan, Hailing [1 ]
Sun, Daolai [1 ]
Yamada, Yasuhiro [1 ]
Sato, Satoshi [1 ]
机构：
[1] Chiba Univ, Grad Sch Engn, Inage Ku, Chiba 2638522, Japan
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 48卷
关键词：
2,3-Butanediol; Dehydration; 3-Buten-2-ol; Monoclinic ZrO2; EARTH-OXIDE CATALYSTS; SELECTIVE DEHYDRATION; 1,4-BUTANEDIOL; CEO2; SURFACE; ALCOHOLS; DIOLS; CERIA;
D O I：
10.1016/j.catcom.2014.01.018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vapor-phase catalytic dehydration of 2,3-butanediol was investigated over metal oxides such as CeO2, La2O3, Yb(2)O3, ZrO2, Al2O3, TiO2, ZnO, Fe2O3, NiO, and Cr2O3. In the dehydration of 2,3-butanedio13-buten-2-ol was preferentially produced over monoclinic ZrO2 along with major by-products such as butanone and 3-hydroxy-2-butanone. Over ZrO2 calcined at 900 degrees C, 3-buten-2-ol was produced with a maximum selectivity of 59.0% at 300 degrees C without producing 1,3-butadiene. (C) 2014 Elsevier B.V. All rights reserved.
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页码：1 / 4
页数：4
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