Production of Ultrahigh-Molecular-Weight Polyethylene/Pristine MWCNT Composites by Half-Titanocene Catalysts

被引:39
作者
Park, Sungjin
Choi, Insung S. [1 ,2 ,3 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Dept Bio & Brain Engn, Taejon 305701, South Korea
关键词
CARBON NANOTUBES; MECHANICAL-PROPERTIES; NANOCOMPOSITES; POLYMERIZATION; FABRICATION; FIBER; FILMS;
D O I
10.1002/adma.200801674
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MWCNT/Ultrahigh-molecular-weight polyethylene (UHMWPE) composites, where pristine MWCNTs are well dispersed in the UHMWPE matrices, are produced using MWCNT/half-titanocene hybrids as catalysts. The diameter of the UHMWPE-coated MWCNT strands produced is about 30-70 nm, while the diameter of the pristine MWCNTs used is 10-15 nm. UHMWPE composites with a molecular weight greater than 2 x 10(6) are produced.
引用
收藏
页码:902 / +
页数:5
相关论文
共 27 条
[11]  
Geng HZ, 2002, ADV MATER, V14, P1387, DOI 10.1002/1521-4095(20021002)14:19<1387::AID-ADMA1387>3.0.CO
[12]  
2-Q
[13]   Properties of crosslinked ultra-high-molecular-weight polyethylene [J].
Lewis, G .
BIOMATERIALS, 2001, 22 (04) :371-401
[14]   Polyethylene multiwalled carbon nanotube composites [J].
McNally, T ;
Pötschke, P ;
Halley, P ;
Murphy, M ;
Martin, D ;
Bell, SEJ ;
Brennan, GP ;
Bein, D ;
Lemoine, P ;
Quinn, JP .
POLYMER, 2005, 46 (19) :8222-8232
[15]   Polymer nanocomposites containing carbon nanotubes [J].
Moniruzzaman, Mohammad ;
Winey, Karen I. .
MACROMOLECULES, 2006, 39 (16) :5194-5205
[16]   Carbon nanotubes as a ligand in CP2ZrCl2-based ethylene polymerization [J].
Park, S ;
Yoon, SW ;
Lee, KB ;
Kim, DJ ;
Jung, YH ;
Do, Y ;
Paik, HJ ;
Choi, IS .
MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (01) :47-50
[17]   Immobilization of Ti(OiPr)4 onto silicon oxide surfaces and surface-initiated polymerization of ε-caprolactone [J].
Park, Sungin ;
Chi, Young Shik ;
Choi, Insung S. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (11) :3711-3716
[18]   Pristine multiwalled carbon nanotube/polyethylene nanocomposites by immobilized catalysts [J].
Park, Sungjin ;
Yoon, Seung Woong ;
Choi, Heechol ;
Lee, Joon Sung ;
Cho, Woo Kyung ;
Kitn, Jinhee ;
Park, Hyung Ju ;
Yun, Wan Soo ;
Choi, Cheol Ho ;
Do, Youngkyu ;
Choi, Insung S. .
CHEMISTRY OF MATERIALS, 2008, 20 (14) :4588-4594
[19]  
Shaffer MSP, 1999, ADV MATER, V11, P937, DOI 10.1002/(SICI)1521-4095(199908)11:11<937::AID-ADMA937>3.0.CO
[20]  
2-9