Organolanthanide catalyzed regio- and stereoselective dimerization of terminal alkynes and polymerization of aromatic diynes

被引：88

作者：

Nishiura, M ^{[1
]}

Hou, ZM ^{[1
]}

机构：

[1] RIKEN, Organomet Chem Lab, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 213卷 / 01期

关键词：

alkyne dimerization; diyne polymerization; lanthanide complex; alkynide complex; polyenyne;

D O I：

10.1016/j.molcata.2003.10.053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This mini review describes recent advances in the application of organolanthanide complexes toward dimerization of terminal alkynes and polymerization of aromatic diynes. The regio- and stereoselectivity in these reactions can be controlled by tuning the ancillary ligands and the central metals of the catalysts. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：101 / 106

页数：6

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