Electrocatalytic oxidation of captopril using a carbon-paste electrode modified with copper-cobalt hexacyanoferrate

被引：10
作者：
Jalali, Fahimeh [1 ]
Ranjbar, Sedigheh [1 ]
机构：
[1] Razi Univ, Dept Chem, Kermanshah 67346, Iran
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2014年 / 50卷 / 05期
基金：
欧盟地平线“2020”;
关键词：
captopril; copper-cobalt hexacyanoferrate; modified electrode; electrocatalytic oxidation; FILM-MODIFIED ELECTRODE; MODIFIED GLASSY-CARBON; LIQUID-CHROMATOGRAPHY; PRUSSIAN BLUE; ELECTROCHEMICAL PREPARATION; CAPILLARY-ELECTROPHORESIS; SELECTIVE ELECTRODE; ASCORBIC-ACID; SENSOR; NICKEL;
D O I：
10.1134/S1023193513120082
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A carbon-paste electrode was modified with copper-cobalt hexacyanoferrate by consecutive potential cycling. The kinetic parameters were calculated for the electroactive species. The resulting electrode exhibited electrocatalytic activity towards the oxidation of captopril. The kinetics of the electrocatalytic reaction was studied. A linear relationship was observed between anodic current and the concentration of captopril in the range of 5.0 x 10(-6)-3.1 x 10(-5) mu M with a detection limit of 4.2 mu M (S/N = 3). The modified electrode was used in the analysis of captopril tablets successfully.
引用
收藏
页码：482 / 489
页数：8
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