Rapid intersystem crossing in highly phosphorescent iridium complexes

被引：150

作者：

Tang, KC ^{[1
]}

Liu, KL ^{[1
]}

Chen, IC ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 386卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.01.098

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Femtosecond time-resolved absorption measurements on Ir complexes are performed. On excitation at wavelength 400 nm, singlet metal-to-ligand charge-transfer (MLCT) states are excited. On probing at 580 nm, a transient absorption appears with time constant 70-100 fs. This transient state rising rapidly but decaying very slowly is assigned to be the lowest triplet MLCT state. Accordingly intersystem crossing in these Ir complexes is rapid. Measured with a nanosecond laser, emission from the lowest triplet MLCT state decays with lifetimes 1.55, 1.65 and 1.7 mus for Ir(PPY)(3), Ir(DBQ)(2)(acac) and Ir(MDQ)(2)(acac), respectively. On 266-nm excitation with a femtosecond laser, high-energy states with mostly pi-pi* character (ligand-centered states) are accessed; they relax to the lowest triplet MLCT state with time constant 100-350 fs. The efficient flow of energy from high-energy electronic states to (MLCT)-M-3 results in high quantum yield in electroluminescent phosphorescence in organic light-emitting diodes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：437 / 441

页数：5

共 19 条

[1] High-efficiency organic electrophosphorescent devices with tris(2-phenylpyridine)iridium doped into electron-transporting materials [J].