Preparation of Sulfur-Modulated Nickel/Carbon Composites from Lignosulfonate for the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

被引：58

作者：

Kong, Fanhao ^{[1
]}

Wang, Min ^{[1
]}

机构：

[1] Dalian Univ Technol, Zhang Dayu Sch Chem, Dalian 116024, Liaoning, Peoples R China

来源：

ACS APPLIED ENERGY MATERIALS | 2021年 / 4卷 / 02期

基金：

中国国家自然科学基金;

关键词：

hydroxymethylfurfural; electro-oxidation; nickel; sulfur modulation; lignosulfonate; ELECTROCHEMICAL OXIDATION; HYDROGEN-PRODUCTION; REACTION DYNAMICS; CATALYSTS; NICKEL; WATER; EFFICIENCY; CONVERSION; ENERGY;

D O I：

10.1021/acsaem.0c02418

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) is a promising way to produce 2,5-furandicarboxylic acid (FDCA). Here, a flowerlike hybrid composed of sulfur-modulated metallic nickel nanoparticles coupled with carbon frameworks (S-Ni@C) is synthesized via two steps, achieving high selectivity and efficiency for HMF oxidation. Lignosulfonate, which is pulp waste, is used as a carbon and sulfur precursor. The optimized S-Ni@C electrode exhibits a nearly 100% conversion of HMF, 96% yield of FDCA, and 96% high faradaic efficiency. This work provides insights into the design and synthesis of electrocatalysts for biomass upgrading.

引用

页码：1182 / 1188

页数：7

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