Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 2. Oxidation of cyclopentene to cyclopentanone

被引：62

作者：

Dubkov, KA ^{[1
]}

Panov, GI ^{[1
]}

Starokon, EV ^{[1
]}

Parmon, VN ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2002年 / 77卷 / 01期

关键词：

cyclopentanone; cyclopentene; nitrous oxide; oxidation;

D O I：

10.1023/A:1020372726494

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A very efficient way of cyclopentanone production via selective liquid phase oxidation of cyclopentene with nitrous oxide is reported. When contacting liquid cyclopentene at high temperature, nitrous oxide is able to interact directly with the C=C double bond of the hydrocarbon and transfer its oxygen to unsaturated carbon atom. The reaction occurs without catalyst with nearly 100% selectivity.

引用

页码：197 / 205

页数：9

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