Syntheses and Crystal Structures of Mn(II) and Ca(II) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid

被引：1
|
作者：
Wang Gui-Xian [1 ,2 ]
Cao Ke-Li [2 ]
Xia Yan [2 ]
Feng Yun-Long [2 ]
机构：
[1] Lishui Univ, Dept Chem & Chem Engn, Lishui 323000, Zhejiang, Peoples R China
[2] Zhejiang Normal Univ, Coll Chem & Life Sci, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 12期
关键词：
coordination polymer; 5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid; crystal structure; luminescent property; METAL-ORGANIC FRAMEWORKS;
D O I：
10.11862/CJIC.2015.311
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal-organic coordination polymers {[MnL]center dot 0.5H(2)O}(n) (1), {[CaL(H2O)(2)]center dot H2O}(n) (2) (H2L=5-(4(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid) have been synthesized under solvothermal reaction and characterized by single crystal X-ray diffraction analysis. 1 features a novel 3D supramolecular network built by different monochiral sheets with (3,3)-connected 2D net. 2 displays a 1D inorganic-chain linked by carboxylate oxygen atoms of L2- with Ca (II) ions. Thermogravimetric analyses (TGA) have been measured for 1 and 2. Luminescent properties of 2 were investigated. CCDC: 1059223, 1; 1059224, 2.
引用
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页码：2337 / 2342
页数：6
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