Synthesis and crystal structure of s-cis-(ethylenediamine-N,N′-diacetato)cobalt(III) complex with N,N-dimethylglycine

被引：4

作者：

Dinovic, VM

Bogdanovic, GA

Novakovic, S

Sabo, TJ

机构：

[1] Univ Belgrade, Fac Chem, YU-11001 Belgrade, Yugoslavia

[2] Inst Sci Nucl, VINCA, Lab Theoret Phys & Condensed Matter Phys, YU-11001 Belgrade, Yugoslavia

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2002年 / 32卷 / 06期

关键词：

D O I：

10.1081/SIM-120013022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The s-cis-geometrical isomer of the cobalt(III) complex with N,N-dimethylglycine (dmgly) and the tetradentate ligand ethylenediamine-N,N'-diacetate ion (edda) was prepared by a direct synthesis from cobalt(II) chloride hexahydrate, N,N-dimethylglycine and edda in the presence of lead(IV) oxide. The complex has been isolated chromatographically and characterized by elemental analyses, electron absorption spectra, infrared spectra and X-ray diffraction analysis.

引用

页码：1085 / 1097

页数：13

共 35 条

[1] COBALT(III) COMPLEXES WITH TRIPOD-LIKE QUADRIDENTATE LIGANDS .3. ABSORPTION AND CIRCULAR-DICHROISM SPECTRA OF COBALT(III) COMPLEXES CONTAINING N-(2-AMINOETHYL)IMINODIACETATE AND AMINO CARBOXYLATE OR 1,2-DIAMINE [J].