Synthesis and physicochemical characterizations of nanostructured Pd/carbon-clinoptilolite-CeO2 catalyst for abatement of xylene from waste gas streams at low temperature

被引：20

作者：

Jamalzadeh, Zeinab ^{[1
,2
]}

Haghighi, Mohammad ^{[1
,2
]}

Asgari, Nazli ^{[1
,2
]}

机构：

[1] Sahand Univ Technol, Dept Chem Engn, Tabriz, Iran

[2] Sahand Univ Technol, RCRC, Tabriz, Iran

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2014年 / 20卷 / 05期

关键词：

Pd/carbon-clinoptilolite-CeO2; Pine cone; ZnCl2; Catalytic oxidation; Xylene; ACTIVATED CARBON; NATURAL ZEOLITES; TOTAL OXIDATION; PHOTOCATALYTIC DEGRADATION; AROMATIC-HYDROCARBONS; VOCS REMOVAL; CLINOPTILOLITE; ADSORPTION; SELECTIVITY; COMBUSTION;

D O I：

10.1016/j.jiec.2013.11.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Xylene removal from waste gas streams was carried out via catalytic oxidation over Pd/carbon-clinoptilolite-CeO2. The synthesized samples were characterized by XRD, FESEM, BET, FTIR and TG techniques. The XRD patterns confirmed the formation of nano ceria with an average crystallite size of 11.6 nm. FESEM results indicated a good morphology for prepared carbon with deep pores, confirmed structure modification of zeolite, and showed that nanocatalyst has nanometric particles with an average size of 60.85 nm. Reaction data illustrated 98% abatement of xylene at 250 degrees C. The stability test of catalyst demonstrated that the removal efficiency has remained constant for 1200 min. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：2735 / 2744

页数：10

共 56 条

[1]

Abbasi Z., 2011, ASIA-PAC J CHEM ENG, P868

[2] Synthesis and Physicochemical Characterization of Nanostructured Pt/CeO2 Catalyst Used for Total Oxidation of Toluene [J].

Abbasi, Zahra ;

Haghighi, Mohammad ;

Fatehifar, Esmaeil ;

Saedy, Saeed .

INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2011, 9

[3] Synthesis and physicochemical characterizations of nanostructured Pt/Al2O3-CeO2 catalysts for total oxidation of VOCs [J].

Abbasi, Zahra ;

Haghighi, Mohammad ;

Fatehifar, Esmaeil ;

Saedy, Saeed .

JOURNAL OF HAZARDOUS MATERIALS, 2011, 186 (2-3) :1445-1454

[4] Application of natural zeolites in the purification and separation of gases [J].

Ackley, MW ;

Rege, SU ;

Saxena, H .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 61 (1-3) :25-42

[5] A physiologically based toxicokinetic model of inhalation exposure to xylenes in Caucasian men [J].

Adams, JC ;

Dills, RL ;

Morgan, MS ;

Kalman, DA ;

Pierce, CH .

REGULATORY TOXICOLOGY AND PHARMACOLOGY, 2005, 43 (02) :203-214

[6] Oxygen defects: The key parameter controlling the activity and selectivity of mesoporous copper-doped ceria for the total oxidation of naphthalene [J].

Aranda, Asuncion ;

Agouram, Said ;

Lopez, Jose M. ;

Mastral, Ana M. ;

Sellick, David R. ;

Solsona, Benjamin ;

Taylor, Stuart H. ;

Garcia, Tomas .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 127 :77-88

[7]

Armbruster T., 2001, Zeolites and mesoporous materials at the dawn o f the 21st century. Studies in Surface Science and Catalysis, V135, P13, DOI [DOI 10.1016/S0167-2991(01)81183-6, 10.1016/s0167-2991, DOI 10.1016/S0167-2991]

[8]

Asgari N., 2012, ENV PROGR SUSTAINABL, V32, P587

[9] Synthesis and physicochemical characterization of nanostructured Pd/ceria-clinoptilolite catalyst used for p-xylene abatement from waste gas streams at low temperature [J].

Asgari, Nazli ;

Haghighi, Mohammad ;

Shafiei, Sirous .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2013, 88 (04) :690-703

[10] The effect of various treatment conditions on natural zeolites: Ion exchange, acidic, thermal and steam treatments [J].

Ates, Ayten ;

Hardacre, Christopher .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 372 :130-140

← 1 2 3 4 5 6 →