Selective B(4)-H Activation of an o-Carboranylthioamide Based on a Palladium Precursor

被引：21
作者：
Wang, Yin-Ping [1 ]
Zhang, Long [1 ]
Lin, Yue-Jian [1 ]
Li, Zhen-Hua [1 ]
Jin, Guo-Xin [1 ]
机构：
[1] Fudan Univ, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 08期
基金：
美国国家科学基金会;
关键词：
B(4)-H activation; o-carborane; palladium precursor complex; selectivity; METAL-MEDIATED FUNCTIONALIZATION; HALF-SANDWICH COMPLEXES; B-H; CARBORANE DERIVATIVES; CAGE; BORON; IRIDIUM; FACILE; RHODIUM; BONDS;
D O I：
10.1002/chem.201603851
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium(II)-induced selective B(4)-H activation of an o-carboranylthioamide has been developed. A tetranuclear palladium(II) complex has been obtained in high yield with excellent regioselectivity. DFT calculations have con-firmed that the B(4)-borometalate is lower in energy than the corresponding B(3)-borometalate. The product proved to be a good precursor for target mononuclear or trinuclear B(4)-H activated complexes.
引用
收藏
页码：1814 / 1819
页数：6
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