Stereoocntrolled synthesis of trans-2-hydroxymethyl-3-methylcyclopentanone from (S)-(+)-citronellene

被引：8

作者：

Stepanov, AV ^{[1
]}

Veselovsky, VV ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 02期

关键词：

(S)-(+)-citronellene; trans-2-hydroxymethyl-3-methylcyclopentanone; (S)-3-methyl-6-nitrohex-1-ene; silyl nitronates; intramolecular [3+2] cycloaddition; cyclopenta[c]isoxazolidine; cyclopenta[c]dihydroisoxazole; sesquiterpenes of the acorane series;

D O I：

10.1023/A:1015484416829

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple route to trans-2-hydroxymethyl-3-methylcyclopenta none was proposed. The compound is a key intermediate in the synthesis of natural spirocyclic sesquiterpene of the acorane series.

引用

页码：359 / 361

页数：3