Stereoocntrolled synthesis of trans-2-hydroxymethyl-3-methylcyclopentanone from (S)-(+)-citronellene

被引：8
|
作者：
Stepanov, AV [1 ]
Veselovsky, VV [1 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 02期
关键词：
(S)-(+)-citronellene; trans-2-hydroxymethyl-3-methylcyclopentanone; (S)-3-methyl-6-nitrohex-1-ene; silyl nitronates; intramolecular [3+2] cycloaddition; cyclopenta[c]isoxazolidine; cyclopenta[c]dihydroisoxazole; sesquiterpenes of the acorane series;
D O I：
10.1023/A:1015484416829
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple route to trans-2-hydroxymethyl-3-methylcyclopenta none was proposed. The compound is a key intermediate in the synthesis of natural spirocyclic sesquiterpene of the acorane series.
引用
收藏
页码：359 / 361
页数：3
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