Iron-silver oxide nanoadsorbent synthesized by co-precipitation process for fluoride removal from aqueous solution and its adsorption mechanism

被引：64
作者：
Azari, Ali [1 ]
Kalantary, Roshanak Rezaei [2 ]
Ghanizadeh, Ghader [3 ]
Kakavandi, Babak [4 ]
Farzadkia, Mahdi [2 ]
Ahmadi, Ehsan [1 ]
机构：
[1] Univ Tehran Med Sci, Sch Publ Hlth, Dept Environm Hlth Engn, Tehran, Iran
[2] Iran Univ Med Sci, Sch Publ Hlth, Dept Environm Hlth Engn, Tehran, Iran
[3] Baqiyatallah Univ Med Sci, Hlth Res Ctr, Tehran 1471613151, Iran
[4] Ahvaz Jundishapur Univ Med Sci, Sch Publ Hlth, Dept Environm Hlth Engn, Ahvaz, Iran
来源：
RSC ADVANCES | 2015年 / 5卷 / 106期
关键词：
DRINKING-WATER; NITRATE REDUCTION; MIXED-OXIDE; PD-CU; FE; DEFLUORIDATION; NANOPARTICLES; ADSORBENT; COMPOSITE; EQUILIBRIUM;
D O I：
10.1039/c5ra17595j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fe-Ag magnetic binary oxide nanoparticles (Fe-Ag MBON) are prepared with co-precipitation of ferric and ferrous chloride solutions, and used for the adsorption of fluoride from aqueous solution. The surface morphology of the adsorbent was characterized by XRD, SEM, TEM, FTIR, XPS, EDX, BET, DLS and VSM techniques. Batch method was followed to optimize the conditions for the removal of fluoride. The results showed maximum removal occurred at pH 3.0 and adsorption equilibrium was achieved within 20 min. Chemical kinetics of the adsorption were well fitted by pseudo-second order models (R-2 > 0.968) and the adsorption process followed the Langmuir isotherm model well (R-2 > 0.976). The fluoride adsorption capacity of Fe-Ag MBON was 22.883 mg g(-1), and decreased with increasing the temperature. Thermodynamic values revealed that the fluoride adsorption process was spontaneous and exothermic. Regeneration experiments were carried out for six cycles and the results indicate a removal efficiency loss of <22%.
引用
收藏
页码：87377 / 87391
页数：15
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